Tlhahiso ea theknoloji ea ts'ebetso le tlhaloso ea fektheri ea tlhahiso ea haeterojene ea khase ea tlhaho (1)
1) Setšoantšo sa motheo sa phallo ea ts'ebetso ea tlhahiso ea haeterojene ea khase ea tlhaho
Ela Hloko: Lebokose le nang le matheba ke sebaka sa moedi wa tlhahiso ea haeterojene sesebediswa, mme morekisi o ikarabella bakeng sa sebaka se ka hara lebokose le nang le matheba.
2) Molao-motheo oa Ts'ebetso
Sekepe se kentsoeng ka skid tlhahiso ea haeterojene ea khase ea tlhaho Lisebelisoa li kenyelletsa haholo-holo mehato e mehlano e meholo ea ts'ebetso: khatello ea khase ea tlhaho, ho tlosoa ha sebabole se setle sa khase ea tlhaho, ho fetola mouoane oa khase ea tlhaho, phetoho ea CO, le karohano le tlhoekiso ea haeterojene.
1) Ho tlosa sebabole linthong tse tala
Khase ea tlhaho e tala e futhumatsoa ho fihlela ho 320-380℃ karolong ea convection ea reformer ebe e feta ka har'a manganese oxide le zinc oxide desulfurizers ho tlosa sebabole sa tlhaho le H2C.2S ka khase e tala ho ka tlase ho 0.1ppm ho fihlela litlhoko tsa sebabole tsa catalyst e fetolang mouoane. Likarabelo tse kholo ke tse latelang:
H2S +ZnO→ ZnS + H2THE
2) Ho fetola mouoane oa khase ea tlhaho: Kamora hore sebabole sa khase ea tlhaho se tlosoe ho fihlela ka tlase ho 0.1 PPm, se kopanngoa le mouoane oa ts'ebetso ka karolelano ea 3.2 ho isa ho 3.5, 'me se kena ka har'a coil ea ho futhumatsa khase e tsoakiloeng hore se futhumatsoe ho fihlela ho 550 ho isa ho 600 °C pele se kena ka har'a tube ea ho fetola. Ka har'a bethe ea catalyst, methane e arabela le mouoane oa metsi ho hlahisa H2 le CO, mme CO e ntse e tswela pele ho arabela le mouwane wa metsi ho hlahisa CO2. Mocheso o hlokahalang bakeng sa ho fetola methane o fanoa ke ho chesoa ha khase e tsoakiloeng ea mafura. Ha ho na le nickel catalyst, liketso tsa eona tse ka sehloohong ke tse latelang:
CH4 +H2O (mouoane) = CO +3H2 -49200Kcal/Kmol (karabelo ea phetoho)
CO+H2O (mouoane) = CO2 +H2+9840Kcal/Kmol (karabelo ea phetoho)
Karabelo ea ho petsoha ha li-alkanes tse phahameng (400 ～ 600 ℃)
CnH2n + 2nH2O (mouoane) =(2n+1) H2 + nCO
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