Hengzhong hydrogen production unit for natural gas

Short Description:

The hydrogen production process of natural gas mainly includes four processes: feed gas pretreatment, natural gas steam conversion, carbon monoxide conversion and hydrogen purification.


Product Detail

Introduction

The hydrogen production process of natural gas mainly includes four processes: feed gas pretreatment, natural gas steam conversion, carbon monoxide conversion and hydrogen purification.

The first step is the raw material pretreatment . The pretreatment here mainly refers to the desulfurization of the raw gas. In the actual process operation, the natural gas cobalt molybdenum hydrogenation series zinc oxide is generally used as the desulfurizer to convert the organic sulfur in the natural gas into inorganic sulfur and then remove it. The flow of raw natural gas treated here is large, so the natural gas source with high pressure can be used or a large margin can be considered when selecting the natural gas compressor.

The second step is the steam conversion of natural gas. Nickel catalyst is used in the reformer to convert alkanes in natural gas into feed gas with main components of carbon monoxide and hydrogen.

Then, carbon monoxide is converted to react with water vapor in the presence of catalyst to generate hydrogen and carbon dioxide to obtain the conversion gas whose main components are hydrogen and carbon dioxide. According to the different conversion temperature, the conversion process of carbon monoxide can be divided into two types: medium temperature conversion and high temperature conversion. The high temperature conversion temperature is about 360 ℃, and the medium temperature conversion process is about 320 ℃.With the development of technical countermeasures, the two-stage process setting of carbon monoxide high-temperature conversion and low-temperature conversion has been adopted in recent years, which can further save the consumption of resources. However, for the case that the carbon monoxide content in the conversion gas is not high, only medium temperature conversion can be adopted.

The last step is to purify hydrogen. Now the most commonly used hydrogen purification system is PAS system, also known as PSA purification and separation system. This system has low energy consumption, simple process and high purity of hydrogen production. At the highest, the purity of hydrogen can reach 99.99%.

Main process equipment

S/N Equipmentname Mainspecifications Main materials Unit weight ton QTY Remarks
Natural gas steam conversion section          
1 Reformer furnace       1 set  
  Thermal load Radiation section: 0.6mW        
    Convection section: 0.4mw        
  Burner Heat load: 1.5mw/set compound material   1  
  High temperature reformer tube   HP-Nb      
  Upper pigtail   304SS   1 set  
  Lower pigtail   Incoloy   1 set  
  Convection section heat exchanger          
    Preheating of mixed raw materials 304SS   1 group  
    Feed gas preheating 15CrMo   1 group  
    Flue gas waste boiler 15CrMo   1 group  
  Manifold   Incoloy   1 group  
2 chimney DN300 H=7000 20#   1  
    Design temperature: 300 ℃        
    Design pressure: ambient pressure        
3 Desulfurization tower Φ400 H=2000 15CrMo   1  
    Design temperature: 400 ℃        
    Design pressure: 2.0MPa        
4 Conversion gas waste boiler Φ200/Φ400 H=3000 15CrMo   1  
    Design temperature: 900 ℃ / 300 ℃        
    Design pressure: 2.0MPa        
    Heat load: 0.3mw        
    Hot side: high temperature conversion gas        
    Cold side: boiler water        
5 Boiler feed pump Q=1m3/h 1Cr13   2 1+1
    Design temperature: 80 ℃        
    Inlet pressure: 0.01Mpa        
    Outlet pressure: 3.0MPa        
    Explosion proof motor: 5.5kw        
6 Boiler feed water preheater Q=0.15MW 304SS/20R   1 Hairpin
    Design temperature: 300 ℃        
    Design pressure: 2.0MPa        
    Hot side: conversion gas        
    Cold side: desalted water        
7 Reforming gas water cooler Q=0.15MW 304SS/20R   1  
    Design temperature: 180 ℃        
    Design pressure: 2.0MPa        
    Hot side: conversion gas        
    Cold side: circulating cooling water        
8 Reforming gas water separator Φ300 H=1300 16MnR   1  
    Design temperature: 80 ℃        
    Design pressure: 2.0MPa        
    Demister: 304SS        
9 Dosing System phosphate Q235   1 set  
    Deoxidizer        
10 Desalination tank Φ1200 H=1200 Q235   1  
    Design temperature: 80 ℃        
    Design pressure: ambient pressure        
11 Natural gas compressor Exhaust volume: 220m3 / h        
    Suction pressure: 0.02mpag        
    Exhaust pressure: 1.7mpag        
    Oil free lubrication        
    Explosion proof motor        
    Motor power: 30KW        
12 Natural gas buffer tank Φ300 H=1000 16MnR   1  
    Design temperature: 80 ℃        
    Design pressure: 0.6MPa        
PSA part          
1 Adsorption tower DN700 H=4000 16MnR   5  
    Design temperature: 80 ℃        
    Design pressure: 2.0MPa        
             
2 Desorption gas buffer tank DN2200 H=10000 20R   1  
    Design temperature: 80 ℃        
    Design pressure: 0.2MPa        

 

天然气制氢橇300Nm3 per hour 5

 


  • Previous:
  • Next: